Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal

By W G Frankenburg; V I Komarewsky; Eric K Rideal


content material: entrance hide; Advances in Catalysis and comparable matters, quantity III; Copyright web page; Contents; members to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. advent; II. The Multiplet concept; III. dialogue of the idea; IV. Steric issues in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically lively Solids; I. advent; II. normal rules; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. comparable platforms; XI. Self-Supported structures; XII. Ferromagnetism; XIII. identity of Ferromagnetic levels; XIV. response procedures; XV. answer strategies; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. advent; II. situation of Air and Acetylene; III. Acetylene elimination; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation by means of Silver Nitrate; References; bankruptcy four. The Poisoning of metal Catalysts I. Catalysts liable to PoisoningII. important sorts of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. additional elements Influencing Toxicity; V. useful Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. advent; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. dimension of the "Acidity" of Cracking Catalysts; III. id of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response charges and Selectivity in Catalyst Pores; I. advent; III . The actual photo of the Pore constitution; III. Mechanism of shipping in Catalyst Pores; IV. actual components making a choice on response premiums on Porous Catalysts . (Definition of expense Constants, the basic Differential Equation and the legislations of Conservation of Mass V. response premiums in unmarried PoresVI. response premiums on functional Catalyst Pellets; VII. response charges on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impression of Pore constitution on Catalyst Selectivity; Appendix; word list of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. advent; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. training of Nickel Sulfide Catalysts; VII. valuable existence and Regeneration
summary: ADVANCES IN CATALYSIS quantity three

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BALANDIN’S CONTRIBUTION TO HETEROGENEOUS CATALYSIS 25 Emmett, P. , J. Am. Chem. 66, 1029 (1943). Palmer, W. , Proc. Roy. (London)A98, 13 (1920). Constabie, F. , Proc. Roy. (London)AllO, 283 (1926). Ipatieff, V. , Corson, B. , and Kurbatov, J. , J. Phys. Chem. 43,589 (1939). Corson, B. , and Ipatieff, V. , J. Phys. Chem. 46, 431 (1941). Kraus, E. , and Hunt, W. , Mineralogy. McGraw-Hill, New York, 1928. Dilke, M. , Eley, D. , and Maxted, E. , Nature 161, 804 (1948). Dowden, D. , Research 1, 239 (1948).

Mineralogy. McGraw-Hill, New York, 1928. Dilke, M. , Eley, D. , and Maxted, E. , Nature 161, 804 (1948). Dowden, D. , Research 1, 239 (1948). Dowden, D. , Chemistry & Industry 1949, 320. Eley, D. , Chemistry & Industry 1949,320. 33. Mott, N. , The Properties of Metals and Alloys. Oxford University Press, London, 1936. 34. , Rms. Modern Phys. 17, 61 (1945). 34s. Hill, F. , and Selwood, P. , J. Am. Chem. 71,2522 (1949). 35. Roberts, J. , Proc. Roy. (London) A162, 445 (1935). 36. Roberts, J. , Some Problems in Adsorption.

If the oxidation state of an ion may be found by purely chemical studies, then a determination of the magnetic moment may be made t o yield an estimate of the degree of intercation covalence between adjacent ions. It will be shown below that this effect occurs to a considerable degree in supported catalytically active oxides of iron. The effect may also be used to decide whether or not a highly dispersed system may be considered t o be atomically dispersed, that is, in true solid solution, or whether the dispersion is one rather of aggregates instead of single ions.

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